I knew something was terribly wrong with the pose! I knew the hips were completely screwed over and I needed to fix them some day, but I didn't even think about the arm and middle. Well, I did think about the arm and tried my hardest to get into her position—after failing I didn't bother fixing it, giving myself a little bit of artistic freedom.
I love the wonderful face! It's not quite the expression I want but it is positively beautiful.
@xegnma: I love what you did with her! I took it in a slightly different direction with the edits and critique that I've already been given earlier, but you caught what I was hoping to achieve with her attitude.
Thank you so much everyone for all of the help and edits and stuff!
Here's an update trying to resolve some of the pose issues and face catastrophe and stuff. Also, she's supposed to be leaning up against a wall; I just never drew a background. It's a bit rough, but I'll wait to make sure there aren't any more triple-jointed pose strikages that I need to tame before polishing again.