Works now. The main problem I see at the moment is th asymmetry of the face. While you don't want to have a mirrored look, and asymmetry isn't a bad thing in art, for a portrait such as this I'd expect the major features of the face to be more or less symmetrical. From the eyes up it looks like a straight-on perspective, but the slant of the jaw makes the face from the nose down look as if it is slightly turned to our right. So center the features, and be wary of how you utilize AA. You don't want to pillowshade (pillowAA?) or just create a 1 px thick line around some parts. You want to logically think where the AA is needed, or else it just blurs the outlines and details.
