The pipes from the Mario series never read to me as metal, I always saw them as plastic.
Either way, metal has very harsh highlights, meaning they're super bright and shiny, metal is also reflective, meaning it reflects any surface you put it on.

Above is a quick study I did to showcase how metal behaves. Notice how the highlights are super bright and it also becomes lighter the lower it goes, because, as stated, metal is reflective.
Coming back to my first sentence, I've always looked at the pipes as plastic because of how shiny and vibrant they are. There are no naturally green metals, so the pipes, if they were metal, shouldn't really be that shiny. Heavy-duty paint that are used on metals usually give
a matte finish to the surface being painted.

Assuming there were metals that were naturally green, above is an
sloppy edit where I made it super-shiny, the blue doesn't really come from anywhere and the pipe would most likely reflect the orange bricks.