I create my pixel art like this....
FILTER->PIXELATE->MOSAIC......
jajajajajajaja im kiddin!!
the only downside is not being able to make geometric shapes without anti-aliasing.
You can actually do it without AA, just UNCHECK the Anti-Alias option everywhere...
Press M, L o W and unckeck that option.
Press T (font) and select, None in the aa option (which is anti-alias)
I suppose you already know these but...
W, uncheck Contiguous, Tolerance 0, and you can select 1 color from your palette and then change it if you want. This is usefull for sprites and 1 layer stuff...
You can export the PSD into files like PNG, BMP, GIF o whatever.... (if you manage to create sprite animations) - FILE/SCRIPTS
If you also create VECTOR art, you can import to photoshop without AA
a tip,
if your scaling your pixel art try to use 200%, 300%, 400%, etc... or rounded numbers like... 240%, same for rotations... this maybe is a bit meh tip, but just in case! XDD. And as ptoing said... Nearest Neighbor first at all! :X
I use Photoshop because I don't like how GIMP is laid out...
Did you tried Paint.net, is pretty good and similar to photoshop... the main problem i have with that program is...the guy who code the program dont want to create a a photoshop clone (which actually is a lol, cause the program is almost equal). And also you cant config the KEYBOARD SHORTCUT, dont know why, but the guy who code the to program just dont want to add that option...